(Di-tert-butylphosphanyl)bis(diphenylphosphanyl)phosphane
نویسندگان
چکیده
The title phosphane, C(32)H(38)P(4) or (Ph(2)P)(2)P(P(t)Bu(2)), has a P atom that is linked to another three P atoms in a pyramidal configuration; the P-P distances in the range 2.2231 (7)-2.2446 (7) Å indicate that the P-P bonds are single bonds.
منابع مشابه
μ-Carbonato-κ4 O,O′:O′,O′′-bis{[2′-(di-tert-butylphosphanyl)biphenyl-2-yl-κ2 P,C 1]palladium(II)} dichloromethane monosolvate
The title compound, [(μ2-CO3){Pd(P(t-C4H9)2(C12H8)}2]·CH2Cl2, the first CO3-bridged palladium dimer complex reported to date, was obtained while preparing the Pd(0) complex with (2-biphen-yl)P( (t) Bu)2. In the crystal, each palladium dimer is accompanied by a dichloro-methane solvent mol-ecule. Coordination of the carbonate and chelated phosphane ligands gives distorted square-planar environme...
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